SAFETY DATA SHEET
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
PRODUCT
Product Name: SANSTAR-SOL H700S FLUID
Product Description: Aliphatic Hydrocarbon Recommended Use: Reaction Diluent, Solvent
COMPANY IDENTIFICATION
Supplier: Sang Hing Hong Chemicals Ltd.
24 Hour Environmental / Health EmergencyTelephone 13902610546 Supplier General Contact +86 0769-8841 1828
SECTION 2 HAZARDS IDENTIFICATION
This material is hazardous according to regulatory guidelines (see (M)SDS Section 15). CLASSIFICATION:
Flammable liquid: Category 2.
Skin irritation: Category 3. Target organ toxicant (central nervous system): Category 3. Aspiration toxicant: Category 1.
Acute aquatic toxicant: Category 2. Chronic aquatic toxicant: Category 2.
Label: Symbol:
Signal Word: Danger
Hazard Statements:
Physical: H225: Highly flammable liquid and vapor.
Health: H304: May be fatal if swallowed and enters airways. H316: Causes mild skin irritation. H336: May cause drowsiness or dizziness.
Environmental: H411: Toxic to aquatic life with long lasting effects. Precautionary Statements:
Prevention: P210: Keep away from heat/sparks/open flames/hot surfaces. -- No smoking. P233: Keep container tightly closed. P240: Ground / bond container and receiving equipment. P241: Use explosion-proof electrical, ventilating, and lighting equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P261: Avoid breathing mist / vapours. P271: Use only outdoors or in a well-ventilated area. P273: Avoid release to the environment. P280: Wear protective gloves and eye / face protection.
Response: P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303 + P361
+ P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P331: Do NOT induce vomiting. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P370 + P378: In case of fire: Use water fog, foam, dry chemical or carbon dioxide (CO2) for extinction. P391: Collect spillage.
STORAGE: P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P403 + P235: Store in a well-ventilated place. Keep cool. P405: Store locked up.
Disposal: P501: Dispose of contents and container in accordance with local regulations. Contains: Naphtha (petroleum), hydrotreated light
Other hazard information:
PHYSICAL / CHEMICAL HAZARDS
Material can accumulate static charges which may cause an incendiary electrical discharge. Material can release vapours that readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited.
Health Hazards
Mildly irritating to skin. May be irritating to the eyes, nose, throat, and lungs. May cause central nervous system depression.
ENVIRONMENTAL HAZARDS
No additional hazards.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary
from person to person.
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
This material is defined as a complex substance.
Hazardous Substance(s) or Complex Substance(s) required for disclosure
Name
CAS#
Concentration*
GHS Hazard Codes
Naphtha (petroleum), hydrotreated light
64742-49-0
100%
H225, H304, H336, H316,
H411
Hazardous Constituent(s) Contained in Complex Substance(s) required for disclosure
Name
CAS#
Concentration*
GHS Hazard Codes
2,3-DIMETHYLPENTANE
565-59-3
0 - 5%
H225, H304, H336, H315,
H410
3,3-DIMETHYLPENTANE
562-49-2
0 - 1%
H225, H304, H336, H315,
H410
3-ETHYLPENTANE
617-78-7
0 - 5%
H225, H304, H336, H315,
H410
3-METHYLHEXANE
589-34-4
0 - 30%
H225, H304, H336, H315,
H410
Hexane, 2-methyl-
591-76-4
0 - 15%
H225, H304, H336, H315,
H410
METHYLCYCLOHEXANE
108-87-2
0 - 20%
H225, H304, H336, H315,
H411
N-HEPTANE
142-82-5
30 - 45%
H225, H304, H336, H315,
H410
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
SECTION 4 FIRST AID MEASURES
INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.
SKIN CONTACT
Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.
INGESTION
Seek immediate medical attention. Do not induce vomiting.
NOTE TO PHYSICIAN
If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately.
SECTION 5 FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use foam, dry chemical, or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water
FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. If a leak or spill has not ignited, use water spray to disperse the vapours and to protect personnel attempting to stop a leak. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel.
Unusual Fire Hazards: Highly flammable. Vapour is flammable and heavier than air. Vapour may travel across the ground and reach remote ignition sources, causing a flashback fire danger.
Hazardous Combustion Products: Smoke, Fume, Incomplete combustion products, Oxides of carbon FLAMMABILITY PROPERTIES
Flash Point [Method]: -8C (18F) [ ASTM D-56]
Flammable Limits (Approximate volume % in air): LEL: 1.1 UEL: 6.7
Autoignition Temperature: 282C (540F)
SECTION 6 ACCIDENTAL RELEASE MEASURES
Notification Procedures
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
Protective Measures
Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for Personal Protective Equipment.
SPILL MANAGEMENT
Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. All equipment used when handling the product must be grounded.
Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Use clean non-sparking tools to collect absorbed material. Absorb or cover with dry earth, sand or other non-combustible material
and transfer to containers. Large Spills: Water spray may reduce vapour, but may not prevent ignition
in enclosed spaces.
Water Spill: Stop leak if you can do so without risk. Eliminate sources of ignition. If the Flash Point exceeds the Ambient Temperature by 10 deg C or more, use containment booms and remove from the surface by skimming or with suitable absorbents when conditions permit. If the Flash Point does not exceed the Ambient Air Temperature by at least 10C, use booms as a barrier to protect shorelines and allow material to evaporate. Seek the advice of a specialist before using dispersants.
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7 HANDLING AND STORAGE
HANDLING
Avoid contact with skin. Use non-sparking tools and explosion-proof equipment. Potentially toxic/irritating fumes/vapour may be evolved from heated or agitated material. Use only with adequate ventilation. Use proper bonding and/or earthing procedures. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source).
Loading/Unloading Temperature: [Ambient] Transport Temperature: [Ambient]
Transport Pressure: [Ambient]
Static Accumulator: This material is a static accumulator.
STORAGE
Ample fire water supply should be available. A fixed sprinkler/deluge system is recommended. Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well-ventilated area. Outside or detached storage preferred. Storage containers should be earthed and bonded. Drums must be earthed and bonded and equipped with self-closing valves, pressure vacuum bungs and flame arresters.
Storage Temperature: [Ambient]
Suitable Containers/Packing: Tank Cars; Barges; Drums; Tank Trucks
Suitable Materials and Coatings: Carbon steel; Polyethylene; Stainless steel; Polypropylene; Teflon Unsuitable Materials and Coatings: Natural rubber; Butyl rubber; Ethylene-proplyene-diene monomer (EPDM); Polystyrene
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMIT VALUES
Exposure limits/standards (Note: Exposure limits are not additive)
Substance Name
Form
Limit/Standard
Note
Source
Year
2,3-DIMETHYLPENTANE
STEL
1000 mg/m3
China OELs
2008
2,3-DIMETHYLPENTANE
TWA
500 mg/m3
China OELs
2008
2,3-DIMETHYLPENTANE
STEL
500 ppm
ACGIH
2009
2,3-DIMETHYLPENTANE
TWA
400 ppm
ACGIH
2009
3,3-DIMETHYLPENTANE
STEL
1000 mg/m3
China OELs
2008
3,3-DIMETHYLPENTANE
TWA
500 mg/m3
China OELs
2008
3,3-DIMETHYLPENTANE
STEL
500 ppm
ACGIH
2009
3,3-DIMETHYLPENTANE
TWA
400 ppm
ACGIH
2009
3-ETHYLPENTANE
STEL
1000 mg/m3
China OELs
2008
3-ETHYLPENTANE
TWA
500 mg/m3
China OELs
2008
3-ETHYLPENTANE
STEL
500 ppm
ACGIH
2009
3-ETHYLPENTANE
TWA
400 ppm
ACGIH
2009
3-METHYLHEXANE
STEL
1000 mg/m3
China OELs
2008
3-METHYLHEXANE
TWA
500 mg/m3
China OELs
2008
3-METHYLHEXANE
STEL
500 ppm
ACGIH
2009
3-METHYLHEXANE
TWA
400 ppm
ACGIH
2009
Hexane, 2-methyl-
STEL
1000 mg/m3
China OELs
2008
Hexane, 2-methyl-
TWA
500 mg/m3
China OELs
2008
Hexane, 2-methyl-
STEL
500 ppm
ACGIH
2009
Hexane, 2-methyl-
TWA
400 ppm
ACGIH
2009
METHYLCYCLOHEXANE
TWA
400 ppm
ACGIH
2009
N-HEPTANE
STEL
1000 mg/m3
China OELs
2008
N-HEPTANE
TWA
500 mg/m3
China OELs
2008
N-HEPTANE
STEL
500 ppm
ACGIH
2009
N-HEPTANE
TWA
400 ppm
ACGIH
2009
Naphtha (petroleum), hydrotreated
light
Vapour.
RCP -
TWA
346 ppm
1400 mg/m3
Total
Hydrocarbo ns
Sang Hing
Hong
2009
Biological limits
No biological limits allocated.
NOTE: Limits/standards shown for guidance only. Follow applicable regulations.
ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:
Adequate ventilation should be provided so that exposure limits are not exceeded. Use explosion-proof ventilation equipment.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
Half-face filter respirator Type A filter material.
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:
Chemical resistant gloves are recommended. Nitrile
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:
Chemical/oil resistant clothing is recommended.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping.
ENVIRONMENTAL CONTROLS
See Sections 6, 7, 12, 13.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional data.
GENERAL INFORMATION
Physical State: Liquid Form: clear
Colour: Colourless
Odour: mild petroleum/solvent Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15.6 C): 0.696
Density (at 15.6 ºC): 697 kg/m³ (5.82 lbs/gal, 0.7 kg/dm³) Flash Point [Method]: -8C (18F) [ ASTM D-56]
Flammable Limits (Approximate volume % in air): LEL: 1.1 UEL: 6.7 Flammability (Solid, Gas): N/A
Autoignition Temperature: 282C (540F)
Boiling Point / Range: 90C (201F) - 120C (208F) Vapour Density (Air = 1): 3.5 at 101 kPa
VAPOUR PRESSURE: 5.904 kPa (44.39 mm Hg) at 20 C
Evaporation Rate (N-Butyl Acetate = 1): 4.2 pH: N/A
Log Pow (n-Octanol/Water Partition Coefficient): N/D Solubility in Water: Negligible
Viscosity: 0.49 cSt (0.49 mm2/sec) at 40 C | 0.58 cSt (0.58 mm2/sec) at 25C Freezing Point: N/D
Melting Point: N/A Decomposition Temperature: N/D
Oxidising properties: See Hazards Identification Section. OTHER INFORMATION
Pour Point: -57C (-71F) Molecular Weight: 102
Hygroscopic: No
Coefficient of Thermal Expansion: 0.00088 V/V/DEG C
SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions.
CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION
Acute Toxicity
Route of Exposure
Conclusion / Remarks
INHALATION
Toxicity: No end point data.
Minimally Toxic. Based on test data for structurally similar
materials.
Irritation: No end point data.
Elevated temperatures or mechanical action may form vapours,
mist, or fumes which may be irritating to the eyes, nose, throat, or lungs. Based on test data for structurally similar materials.
INGESTION
Toxicity: LD50 > 15000 mg/kg
Minimally Toxic. Based on test data for structurally similar
materials.
Skin
Toxicity: LD50 > 3000 mg/kg
Minimally Toxic. Based on test data for structurally similar
materials.
Irritation: No end point data.
Mildly irritating to skin with prolonged exposure. Based on
test data for structurally similar materials.
Eye
Irritation: No end point data.
May cause mild, short-lasting discomfort to eyes. Based on test
data for structurally similar materials.
OTHER HEALTH EFFECTS FROM SHORT AND LONG TERM EXPOSURE
Anticipated health effects from sub-chronic, chronic, respiratory or skin sensitization, mutagenicity, reproductive toxicity, carcinogenicity, target organ toxicity (single exposure or repeated exposure), aspiration toxicity and other effects based on human experience and/or experimental data.
For the product itself:
Vapour/aerosol concentrations above recommended exposure levels are irritating to the eyes and respiratory tract, may cause headaches, dizziness, anaesthesia, drowsiness, unconsciousness and other central nervous system effects including death. Prolonged and/or repeated skin contact with low viscosity materials may defat the skin resulting in possible irritation and dermatitis. Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema.
Additional information is available by request.
The Following Ingredients are Cited on the Lists Below: None.
--REGULATORY LISTS SEARCHED--
1 = NTP CARC 3 = IARC 1 5 = IARC 2B
2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC
SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials.
ECOTOXICITY
Material -- Expected to be toxic to aquatic organisms. May cause long-term adverse effects in the
aquatic environment.
MOBILITY
Material -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment
and wastewater solids.
PERSISTENCE AND DEGRADABILITY
Biodegradation:
Material -- Expected to be readily biodegradable.
Hydrolysis: Photolysis:
Material -- Transformation due to hydrolysis not expected to be significant. Material -- Transformation due to photolysis not expected to be significant.
Atmospheric Oxidation:
Material -- Expected to degrade rapidly in air
OTHER ECOLOGICAL INFORMATION VOC: Yes
ECOLOGICAL DATA
Component
Acute Aquatic Toxicity
2,3-DIMETHYLPENTANE
L(E)C50 >0.1 - 1 mg/L
3,3-DIMETHYLPENTANE
L(E)C50 >0.1 - 1 mg/L
3-ETHYLPENTANE
L(E)C50 >0.1 - 1 mg/L
3-METHYLHEXANE
L(E)C50 >0.1 - 1 mg/L
Hexane, 2-methyl-
L(E)C50 >0.1 - 1 mg/L
N-HEPTANE
L(E)C50 >0.1 - 1 mg/L
SECTION 13 DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal.
NATIONAL CATALOGUE OF HAZARDOUS WASTES
HW42 - Organic Solvents Wastes
DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products.
Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION
China List of Dangerous Goods (GB 12268 – 2005) Proper Shipping Name:
Hazard Class: 3
UN Number: 1206 Packing Group: II CN Number: 32006
INTERNATIONAL CLASSIFICATION FOR TRANSPORT SEA (IMDG)
Proper Shipping Name:
Hazard Class & Division: 3 EMS Number: F-E, S-D
UN Number: 1206 Packing Group: II Marine Pollutant: Yes Label(s): 3
Transport Document Name:
UN1206, HHEydPrTAocNaErSb,on3,LiPqGuiIdI,, 3(,-8P°GCIIc,.c(.-)8,°MCARIc.NEc.)P,OLMLAURTIANNET POLLUTANT
AIR (IATA)
Proper Shipping Name:
Hazard Class & Division: 3 UN Number: 1206
Packing Group: II Label(s) / Mark(s): 3
Transport Document Name: UN1206, HEPTANES, 3, PG II
SECTION 15 REGULATORY INFORMATION
This material is considered hazardous according to The General Rule for Classification and Hazard Communication of Chemicals (GB 13690-2009).
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS
The General Rules for preparation of precautionary label for Chemicals (GB 15258-2009): Regulated Law of the People's Republic of China on Prevention and Control of Environmental Pollution by Solid
Waste: See Disposal Considerations section.
Complies with the following national/regional chemical inventory requirements: AICS, IECSC, DSL, EINECS, ENCS, KECI, PICCS, TSCA
SECTION 16 OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
KEY TO THE H-CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only):
H225: Highly flammable liquid and vapor; Flammable Liquid, Cat 2 H304: May be fatal if swallowed and enters airways; Aspiration, Cat 1 H315: Causes skin irritation; Skin Corr/Irritation, Cat 2
H316: Causes mild skin irritation; Skin Corr/Irritation, Cat 3
H336: May cause drowsiness or dizziness; Target Organ Single, Narcotic
H410: Very toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 1 H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:
Updates made in accordance with implementation of GHS requirements.
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